- Autor
- Hollauf, Manuel
- Cajlakovič, Merima
- Tscherner, Martin
- Köstler, Stefan
- Knall, Astrid-Caroline
- Trimmel, Gregor
- TitelSynthesis and characterization of naphthalimide-functionalized polynorbornenes
- Datei
- DOI10.1007/s00706-016-1887-3
- Persistent Identifier
- Erschienen inMonatshefte für Chemie - Chemical Monthly
- Band148
- Erscheinungsjahr2017
- Heft1
- Seiten121-129
- ISSN1434-4475
- Download Statistik1912
- Peer ReviewJa
- AbstractHighly fluorescent and photostable (2-alkyl)-1H-benzo[de]isoquinoline-1,3(2H)-diones with a polymerizable norbornene scaffold have been synthesized and polymerized using ring-opening metathesis polymerization. The monomers presented herein could be polymerized in a living fashion, using different comonomers and different monomer ratios. All obtained materials showed good film-forming properties and bright fluorescence caused by the incorporated push--pull chromophores. Additionally, one of the monomers containing a methylpiperazine functionality showed protonation-dependent photoinduced electron transfer which opens up interesting applications for logic gates and sensing.
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