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  • Autor
    • Hollauf, Manuel
    • Cajlakovič, Merima
    • Tscherner, Martin
    • Köstler, Stefan
    • Knall, Astrid-Caroline
    • Trimmel, Gregor
  • TitelSynthesis and characterization of naphthalimide-functionalized polynorbornenes
  • Datei
  • DOI10.1007/s00706-016-1887-3
  • Persistent Identifier
  • Erschienen inMonatshefte für Chemie - Chemical Monthly
  • Band148
  • Erscheinungsjahr2017
  • Heft1
  • Seiten121-129
  • ISSN1434-4475
  • ZugriffsrechteCC-BY
  • Download Statistik395
  • Peer ReviewJa
  • AbstractHighly fluorescent and photostable (2-alkyl)-1H-benzo[de]isoquinoline-1,3(2H)-diones with a polymerizable norbornene scaffold have been synthesized and polymerized using ring-opening metathesis polymerization. The monomers presented herein could be polymerized in a living fashion, using different comonomers and different monomer ratios. All obtained materials showed good film-forming properties and bright fluorescence caused by the incorporated push--pull chromophores. Additionally, one of the monomers containing a methylpiperazine functionality showed protonation-dependent photoinduced electron transfer which opens up interesting applications for logic gates and sensing.